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OIL FIELD CHEMICAL DIVISION


Bentonite

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Bentonite
Specification Of Sodium Based Bentonite
Form Finely Dividend Powder
Colour Creamy White
Fineness (through B.S.S 200 SIEVE) 95%
Odour Slight To More
Swelling Capacity 10-15 ml
Moisture Content 4.5% max
Specific Gravity 1.7 G/ML

Specification Of OCMA Grade Bentonite
Viscometer Dial Reading at 600 RPM 30 Min.
Yield Point/plastic Viscosity Ratio 6.0 Max.
Fluid Loss 16.0 ML.
Residue Greater than 75 Micro 2.5 Wt.% Max
Moisture 12.0% Max

Specification Of DFCP-4 Grade Bentonite
Yield 16.0 m3/tonne
Filtrate loss 15.0 ml max.
Moisture 15.0 wt% max.
Residue Greater than 75 Micro 2.5 Wt.% Max
Dry screen analysis passing through 150 microns 98 % min.

Specification API - 13-A Grade Bentonite
Viscometer Dial Reading at 600 RPM 30 Min.
Yield Point/plastic Viscosity Ratio 3.0 Max.
Fluid Loss 13.0 ML.
Residue Greater than 75 Micro 4.0 Max
Moisture 10.0% Max

Specification Pilling Grade Bentonite
Moisture Content 12%
Loose Bulk Density 0.75 to 0.85 g/l
Residue on 0.075 mm 2.5%
PH value (Suspension 30-40 kg/m3) 10
Concentration Viscosity (kg/m3) 30
Apparent Viscosity (cp) 12
Plastic Viscosity(cp) 7
Marsh Viscosity(sec.) (Swell time-1 Hr.) 32
Gel Strength (lbs/100 SqFt) Shearometer a well time-1 Hr. 0
Filter Loss(ml) (30 min.7 Bar) 25
Swelling Time (Fresh water with about 3.57 meg/1 Cao and/ or Mgo hardness temp.20 degree 20 hrs.








OIL FIELD CHEMICAL DIVISION
Spotting Fluid (Non Weighted)

Description :
In the process of drilling, the drill string becomes differentially stuck, then there are only three options remaining to free it.
  • Mechanical Method.
  • Spotting fluids.
  • Hydrostatic pressure can be reduced. In general, penetration of oil based spotting fluids into the filter cake accompanied by dehydration and cracking results in reduction of a differential pressure across the drill string. Spotting fluids are generally positioned in the open hole to completely cover the problem area.
Specification
Physical State : It should be a coloured liquid.

Miscibility with HSD Oil : Completely miscible.

Interfacial Tension : The interfacial tension of distilled water - HSD oil containing 2.5%(w/v) spotting fluid should not be more than 13 dynes/cm.

Lubricity Coefficient : Lubricity coefficient of bentonite suspension (prepared by dilution of pre-hydrated bentonite with distilled water) having apparent viscosity 15 c.p. & treated with 1% (w/v) of the additive shall not be more than 0.11.

Mud Cake Cracking Test : Prepare a bentonite suspension having apparent viscosity 15c.p. by diluting pre- hydrated bentinite with distilled water and load it to sp.gr. 1.20 with barytes. Obtain a filter cake of this mud in the API filter loss apparent by carrying out filtration for 30 min. using 100 psi pressure. Throw the mud away, wash the mud cake with slow stream of water ( without removing the mud cake from the cell) and fill the cell with 100 ml. HSD oil containing 2.5% (w/v) spotting fluid. Apply 100 psi pressure , after closing the cell and determine the time required for collection of 100 ml. filtrate. The time required should not be more than 50 minutes.

Stickiness Test : Prepare loaded bentonite suspension of sp.gr. 1.20 as in the case of mud cake cracking test & fill in the modified Boroid stickness tester. From a filter cake by applying 500 psi pressure For 30 minutes. Stick the plate by pressing it On the cake for 5 minutes & leave for 1 Hr. Under 500 psi pressure. Then release the Pressure, drain off mud from cell by opening the bottom stopper & fill the cell with 100 ml. oil HSD oil containing 2.5%(w/v) of the sample of spotting fluid, close the top stopper and again apply 500 psi pressure. Note the time for released in 20 minutes, apply torque with torque wrenth. The plate should not require a torque of more than 65 in - lbs. to release it.

Packing : Should be packed in leak proof, sealed M.S.Drums, strong enough to withstand Rigors of transit & storage capacity 200 lts. Per drum.

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E. P. Lubricant

Description :
The frictional resistance generated by rotating the drill string against the formation or casing may require extra torque if the hole is crooked or directional, considerable friction resistance to raising and lowering the drill string may also occur. Under certain conditions, such as in highly deviated holesw, holes with different charges in direction, undergauge holes or poor drill string dynamics, increased torque and drag entail a high risk of lost rig time, expensive pipe recovery operations and limitations in well developemnts. Expensive torque required to rotate the pipe generates greater strain on the drill pipe with the danger of twist - off.

Sometimes, another problem occurs when drill pipe sticks to the wall of bore - hole. This may be caused by running or pulling pipe into the undergauge section of the hole, a key seat or a bridge of caving. Under certain circumstances differential pressure sticking may also occur when the drill pipe becomes motionless against a permiable formation and a portion of the contact area of the pipe is isolated by the filter cake.

To overcome these difficulties, drilling fluids are treated with mud lubricants. Mud lubricants made by Deltamike has following properties.

Chemical Composition : Based on vegetable oils, EP additives and mobility

Specification
1. Physical State : Yellow, brown or blackish coloured liquid.

Solubility :
    Completely miscible with HSD
    Immiscible with water.

Density of 30+2°C : It will be in the range 0.85 - 0.95 gm/ml.

Performance Test :
A. Lubricity Test
- In fresh water mud: Prepare a bentonite suspension, using upto 7.5% (w/v) approved bentonite in distilled water by stirring with a laboratory stirrer(5000 - 6000 rpm) for 30 min. and aging at 30+2°C for 24 hrs and restirring with the same stirrer for 15 min so that the resultant mud has apparent viscosity in the range 15 + 1c.p. To this mud, add 0.5% (w/v) of the material while stirring with above stirrer for 15 min and measure lubricity coefficient tester. It will not be more than 0.15.
- In salt water mud : Prepare a 10% (w/v) bentonite suspension by stirring with a laboratory stirrer (5000 - 6000 rpm) for 30 min and age for 24 hrs. at 30+2°C add 4% (w/v) sodium chloride (L.R. grade) and age for 24 hrs at 30+2°C . Adjust the apparent viscosity of this suspension to 15 + 1 c.p. by dilution with 4% (w/v) sodium chloride solution. Now add 0.5% (w/v) of the material and stir for 5 min with above mentioned stirrer & then determine the lubricity coefficient of the mud. It will not be more than 0.20.

B. Extreme Pressure Lubrication Test :
- In fresh water mud : Prepare the bentonite suspension as in 4(A) (i) and Similarly treat with 0.5% (w/v) of the material while stirring for 15 min. Determine its firm strength at 300 in-lb load with the help of E.P. tester. It will be 25000 psi (minimum).

- In salt water mud : prepare the salt water mud as in 4(A) (iii) and similarly Treat wih 0.5% (w/v) of the material while stirring for 15 min. Determine its film strength at 300 in-lb load with the help of E.P. tester. It will be 20000 psi (minimum).

Foam Test :Prepare the fresh water bentonite suspension as in 4(A) (i) and add 0.5% (w/v) of the material stir for 15 min at high speed in Hamilton Beach Mixer and determine the sp. Gravity of the mud after waiting for 1 min. It should not be less than 0.80.

Packing : The material will be packed in leak proof, sealed, M.S.Drums strong enough to withstand rigours of transit and Storage, capacity 200 litres per drum.

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Surfactant

Description :
LIQUIDET SF is a liquid formulation based on the specifically made surface active agents. It is designd to improve the flow properties of the drilling fluids upto very high bottom temprature. It is a good emulsifier of oil in fresh water and salt water. It improves oil wetting and lubrication resulting in improvement in torque and drag.

LIQUIDET SF plays a very important role in improving the flow properties of fluid. It gets absorbed on the surface of the clay particles. The hydrated Sheath thus absorbed on the clay particles acts as a barrier which drastically limits the inter - surface interaction between the clay particles. This reduces the swelling of the clay and dispersion of shales.

Specification :
  • Physical State : The material will be a non - ionic homogenous liquid free visible impurities.
  • Miscibility of 0.1% V/V sample with 15% w/w HCl and 28% w/w HCl at 24 + 2°C : Miscible.
  • Pour Point °C : 12 (Max).
  • Surface Tension of the 15% (W/W) HCl Acid contaning 200 ppm of the surfactant 25°C dynes/cm : 35 (Max).
  • Compatibility with following acid additives :
    1. Acid Corrosion Inhibitor 1% v/v
    2. Non - Emulsifier 0.5% v/v tested for following :
        - Formation of precipitate : Negative
        - Wettability characteristics : Positive
        - Surface tension at 25°C dynes/cm : 35 (Max).
  • Dosage : 2 - 3 gallons per barrel
  • Packing : 200 litres HDPE - Sea - worthy barrels
  • Handling & Precautions : LIQUIDET SF is a very safe material neutral product, do not consume internally. In case of spillage on the surface, soak it first with saw - duct and then wash with water.
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Emulsifier

Description :
LIQUIDET EMULSE is a very effective emulsifier which contains a blend of special coupling agents. It is compatible with most well stimulations chemicals. It finds application in well stimulation, treating tank bottoms, salt water injection systems, cooling towercleaning, gas storage wells, treating hydraulic lift systems, open salt water pils and cleaning flowlines.

Specification :
  • Physical State : The material will be a non-ionic homogenous liquid free from visible impurities.
  • Miscibility of 0.9% V/V sample with water at 24 ± 2°C : will be miscible
  • Pour Point °C : 12 (Max).
  • Specifications of Scale Inhibitor : 7.5 to 10.5
Emulsification Test :
1. Concentration of emulsifier required to from o/w emulsion utilizing conventional water base gel and high speed diesel in the ratio 1:2 and to obtain following results, ml/litre : 3 (Max).

2. Viscosity of emulsion at 511 sec - shear rate , CP.
    At 24 ± 2°C : 95 (min).
    After aging at 90 ± 2°C for 4 hrs : 5 (max).

3. Flow behaviours index (N') :
    At 24 ± 2°C : 0.7 (max).
    After aging at 90 ± 2°C : 0.99 - 1.00

4. Phase seperation test for emulsion at 4(1) :
    - Temp. of test, °C : 90 + 2
    - Duration of test , hrs : 1
    - Percentage phase seperation by volume : 100 (Min).

    - Temp. of test, °C : 40 + 2
    - Duration of test, hrs : 4
    - Percentage phase seperation by volume : Nil
    - Wettability characteristics of clean sand : preferentially water wet

Compatibility with following additives :
  » 1% W/V potassium chloride in tap water
  » 0.001% W/V ammonium per silphate in tap water
    - Formation of precipitate : Negative
    - Wetability characteristics : Positive
    - Phase seperation test : Positive

Dosage :5.25 ppm on continous method 0.25 to 5% by volume for slug or batch method.

Packing : 200 lts. HDPE - Sea - worthy barrels.

Handling & Precautions :LIQUIDET EMULSE is a very safe material for handling. However , spillage on floors may be highly slippery. Therefore , in case of accidental spillage, absorb the same on the saw - dust and wash with plenty of water.
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Demulsifier

Description :
DEMULSE 507 is a product formulated to give maximum reduction in surface tension & demulsification to well stimulated fluids, in addition to aiding in prevention or destruction of damaging emulsions, DEMULSE 507 exihibits great despassing action and mud thinning property. DEMULSE 507 can also be used in water injection or disposal system.

Specification :
Appeareance : Clear liquid at free 20°C from visible impurities.

Surface tension of 0.20% : 37.8 dynes/cm.

Cloud Point of 0.01% product in 5% NaCl : 87.5°C

Performance Test :
  • 100ml. of emulsion is taken in a stoppered graduated cylinder & emulsion is heated to 45 ± 1°C in water bath.
  • 1% Solution of the demulsifier is added in precalculated volume.
  • Mixing is done by shaking the cylinder lengthwise giving 100 strokes.
  • Doped emulsion is placed in hot water bath is cured for 1 hr. at 60 ± 1°C.
  • After curing the cylinder is taken out of the water bath & oil is drwan from the top layer for water content determination.
  • The water seperation is noted.
  • A blank test is also to be performed simultaneously.
Dosage : 1 ltr./1000 litres of acid, water or brine fracturing liquids prior to pumping into well.

Packing : 200 ltrs. HDPE - Sea - worthy barrels.

Handling & Precautions : DEMULSE 507 is a very safe material for handling. However, spillage on floors may be highly slippery. Therfore, in case of accidental spillage, absorb the same on the saw - dust and wash with plenty of water.

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